Electron Configuration Calculator
How it Works
01Pick the Element
92 elements supported — Hydrogen (Z=1) through Uranium (Z=92)
02Apply Aufbau Order
Fill orbitals lowest-energy first: 1s → 2s → 2p → 3s → 3p → 4s → 3d → ...
03Apply Hund's Rule
Within a subshell, fill each orbital singly with parallel spins before pairing
04Get Full Output
Configuration · noble-gas shorthand · orbital diagram · block · group · anomalies
What is an Electron Configuration Calculator?
Pick the element from the alphabetical dropdown — 92 elements available — and the calculator returns the configuration plus the electron's "address" in the periodic table: atomic number Z, total electron count, period, group, and block (s, p, d, or f). For elements with Aufbau anomalies — Cr, Cu, Nb, Mo, Ru, Rh, Pd, Ag, Pt, Au, Gd, Th — the calculator displays the actual configuration (which deviates from the simple Aufbau prediction) along with a clear explanation of why (extra stability of half-filled or fully filled subshells).
Three rules govern ground-state electron configurations: Aufbau (fill lowest-energy orbitals first), Pauli exclusion (max 2 electrons per orbital, with opposite spins), and Hund's rule (fill orbitals within a subshell singly with parallel spins before pairing). The orbital filling diagram in the output shows all three rules in action — boxes for orbitals, up/down arrows for electron spins, color-coded by subshell type.
Pro Tip: Pair this with our Molar Mass Calculator for stoichiometry, or our Electronegativity Calculator for related bonding analysis.
How to Use the Electron Configuration Calculator?
How do I work out the electron configuration?
Electron configurations follow three rules from quantum mechanics — Aufbau, Pauli exclusion, and Hund. Together they determine the unique ground-state configuration of every element. Here's the complete framework:
Think of orbitals like seats in a stadium with sections (subshells) and rows (energy levels). Aufbau says you fill the cheapest seats first. Pauli says no more than 2 fans per seat (and they must face opposite ways). Hund says you spread out before doubling up. Combined, these three rules give the complete seating chart for any atom.
Rule 1: Aufbau Principle
Electrons fill orbitals in order of increasing energy. The Madelung rule (n + l) gives the order:
1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → 5s → 4d → 5p → 6s → 4f → 5d → 6p → 7s → 5f → 6d → 7p
Note: 4s fills before 3d (because 4s has lower n+l), but once 3d starts filling, 4s and 3d energies become similar and can swap order in some elements (Cr, Cu anomalies).
Rule 2: Pauli Exclusion Principle
No two electrons in an atom can have the same four quantum numbers.
Practical consequence: max 2 electrons per orbital, and they must have opposite spins (one ↑, one ↓). This caps subshell capacities: s = 2 e⁻ (1 orbital), p = 6 e⁻ (3 orbitals), d = 10 e⁻ (5 orbitals), f = 14 e⁻ (7 orbitals).
Rule 3: Hund's Rule of Maximum Multiplicity
Within a subshell, electrons fill each orbital singly (with parallel spins) before any orbital gets a second electron.
Example: nitrogen's 2p³ is three single electrons in the three p orbitals (all spin-up), not two paired in one orbital + one alone. This minimizes electron-electron repulsion and maximizes total spin (lowest energy = ground state).
Aufbau Anomalies (Cr, Cu, Mo, Ag, Au, Pd, Pt, ...)
Some transition metals violate the simple Aufbau prediction because half-filled (d⁵) and fully filled (d¹⁰) subshells have extra exchange-energy stability:
- Chromium (Z=24): [Ar] 3d⁵ 4s¹ not [Ar] 3d⁴ 4s² (half-filled 3d⁵)
- Copper (Z=29): [Ar] 3d¹⁰ 4s¹ not [Ar] 3d⁹ 4s² (filled 3d¹⁰)
- Molybdenum (Z=42): [Kr] 4d⁵ 5s¹ (same logic as Cr)
- Silver (Z=47): [Kr] 4d¹⁰ 5s¹ (same logic as Cu)
- Palladium (Z=46): [Kr] 4d¹⁰ (BOTH 5s electrons promoted — unique among transition metals)
- Platinum (Z=78): [Xe] 4f¹⁴ 5d⁹ 6s¹
- Gold (Z=79): [Xe] 4f¹⁴ 5d¹⁰ 6s¹
- Gadolinium (Z=64): [Xe] 4f⁷ 5d¹ 6s² (half-filled 4f⁷)
Reading the Periodic Table
The periodic table is literally a map of electron configurations. Group 1 is s¹ (alkali metals), Group 2 is s² (alkaline earths), Groups 13–18 are p¹ through p⁶, transition metals (Groups 3–12) are d¹ through d¹⁰, lanthanides and actinides are f-block. Period number = highest occupied energy level (n). The block (s, p, d, f) tells you which subshell is being filled.
Electron Configuration Calculator – Atoms In Practice
- Step 1: Iron has 26 electrons. Apply Aufbau order to fill 26 electrons.
- Step 2: 1s² (2) + 2s² (4) + 2p⁶ (10) + 3s² (12) + 3p⁶ (18) — that's the argon core. Then 4s² (20) + 3d⁶ (26).
- Step 3: Full configuration: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁶ 4s². Noble-gas shorthand: [Ar] 3d⁶ 4s².
- Step 4: 3d⁶ filling: by Hund's rule, fill all 5 d orbitals singly first (5 spin-up electrons), then pair the 6th in the lowest. Result: 4 unpaired electrons in 3d. This explains why iron is paramagnetic and ferromagnetic.
- Step 5: Periodic placement: d-block (transition metal), period 4, group 8. Standard Aufbau, no anomaly.
Now consider the famous chromium anomaly (Cr, Z = 24): simple Aufbau predicts [Ar] 3d⁴ 4s². But the actual ground state is [Ar] 3d⁵ 4s¹. Why? A half-filled 3d⁵ subshell (all 5 d orbitals singly occupied with parallel spins) has extra "exchange-energy" stability. The energy gain from completing the half-filled d outweighs the energy cost of leaving 4s singly occupied. Same logic explains Cu ([Ar] 3d¹⁰ 4s¹), Mo, Ag, Au — all have exceptional stability of d⁵ or d¹⁰ subshells.
For caesium (Cs, Z = 55): [Xe] 6s¹. Single 6s electron — explains why Cs is the most reactive stable alkali metal: that lone 6s electron is far from the nucleus and shielded by 54 inner electrons, so it ionizes easily (lowest first ionization energy of any stable element, ~3.9 eV).
Who Should Use the Electron Configuration Calculator?
Technical Reference
Quantum Numbers. Every electron is described by 4 quantum numbers: n (principal, energy level), l (azimuthal, subshell shape: 0=s, 1=p, 2=d, 3=f), mₗ (magnetic, orbital orientation: −l to +l), and mₛ (spin, ±½). Pauli exclusion: no two electrons share all four. Practical consequence: 2 electrons per orbital, opposite spins.
Subshell Capacities:
- s subshell: 1 orbital × 2 electrons = 2 e⁻ max
- p subshell: 3 orbitals × 2 = 6 e⁻ max
- d subshell: 5 orbitals × 2 = 10 e⁻ max
- f subshell: 7 orbitals × 2 = 14 e⁻ max
Madelung Rule (Aufbau Order). Subshells fill in order of increasing (n + l), with ties broken by lower n. Result:
1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p
Note that 4s (n+l = 4+0 = 4) fills before 3d (n+l = 3+2 = 5) despite higher n. After filling, the 4s electrons are actually higher in energy than 3d electrons — which is why 4s is the FIRST to ionize in transition-metal cations.
Cation Configurations. When a transition metal forms a cation, it loses outer-shell s electrons FIRST, then d electrons. So Fe ([Ar] 3d⁶ 4s²) → Fe²⁺ is [Ar] 3d⁶ (lost both 4s electrons), not [Ar] 3d⁴ 4s². For Fe³⁺: [Ar] 3d⁵ (lost both 4s + one 3d). This is why Fe³⁺ is high-spin with all 5 d electrons unpaired (half-filled stability).
The 19 Known Aufbau Anomalies (gas-phase ground state):
- Cr (24): 3d⁵ 4s¹
- Cu (29): 3d¹⁰ 4s¹
- Nb (41): 4d⁴ 5s¹
- Mo (42): 4d⁵ 5s¹
- Ru (44): 4d⁷ 5s¹
- Rh (45): 4d⁸ 5s¹
- Pd (46): 4d¹⁰ (no 5s electrons!)
- Ag (47): 4d¹⁰ 5s¹
- La (57): 5d¹ 6s² (no 4f)
- Ce (58): 4f¹ 5d¹ 6s²
- Gd (64): 4f⁷ 5d¹ 6s²
- Pt (78): 5d⁹ 6s¹
- Au (79): 5d¹⁰ 6s¹
- Ac (89): 6d¹ 7s² (no 5f)
- Th (90): 6d² 7s² (no 5f)
- Pa (91): 5f² 6d¹ 7s²
- U (92): 5f³ 6d¹ 7s²
- Np (93): 5f⁴ 6d¹ 7s²
- Cm (96): 5f⁷ 6d¹ 7s²
Block Definitions. The block of an element is determined by which subshell is being filled. s-block = Groups 1, 2, plus He (filling ns). p-block = Groups 13–18 (filling np). d-block = Groups 3–12, transition metals (filling (n−1)d). f-block = lanthanides + actinides (filling (n−2)f). Period = highest occupied n.
Key Takeaways
Frequently Asked Questions
What is the Electron Configuration Calculator?
Includes period/group/block placement and explicit explanations of all 19 known Aufbau anomalies (Cr, Cu, Mo, Ag, Au, Pd, Pt, Gd, etc.) where extra stability of half-filled or filled subshells overrides the standard filling order. Designed for chemistry students, inorganic chemists, materials scientists, spectroscopists, and physics students — runs entirely in your browser.
Pro Tip: For more chemistry tools, try our Molar Mass Calculator.
What are the three rules for electron configurations?
What's the difference between full and noble-gas shorthand?
Why is chromium [Ar] 3d⁵ 4s¹ instead of [Ar] 3d⁴ 4s²?
How do I find valence electrons from the configuration?
Why does 4s fill before 3d?
What does the orbital diagram show?
What are the four quantum numbers?
How do I find the configuration of an ion?
Why are noble gases so unreactive?
Are there configurations beyond uranium?
Disclaimer
Configurations shown are ground-state — what you'd find in IUPAC tables and most chemistry textbooks. Excited-state and ionic configurations differ. The 19 known Aufbau anomalies are noted explicitly when they apply. For super-heavy elements (Z > 92), relativistic effects make configurations less certain and theoretical predictions vary; this calculator covers H through U where the configurations are well-established.