Liquid Ethylene Density Calculator
How it Works
01Confirm Cryogenic Conditions
Liquid ethylene exists only between −169.2 °C (triple point) and 9.2 °C (critical point). At standard temp it is a gas.
02Weigh the Sample
Mass of the liquid C₂H₄ in your tank or vessel. Accepts kg / g / mg / lb / oz / metric tons.
03Measure the Volume
Volume of the liquid in L / mL / m³ / ft³ / US gal / UK gal — corrected to the actual storage temperature.
04Apply ρ = m / V
Output in kg/m³, g/mL, lb/ft³, lb/gal — plus % deviation from the 567.7 kg/m³ boiling-point reference.
What is a Liquid Ethylene Density Calculator?
Our Liquid Ethylene Density Calculator implements the foundational identity ρ = mass / volume with full unit support — accept mass in kg / g / mg / lb / oz / metric tons, volume in L / mL / m³ / cm³ / ft³ / US gal / UK gal, and report density in five unit systems: kg/m³ (SI standard for engineering), g/mL = g/cm³ (laboratory standard), kg/L, lb/ft³ (US engineering), and lb/gal (cargo accounting). Every result is compared against the NIST reference density of 567.7 kg/m³ at the 1-atm boiling point of −103.7 °C with explicit % deviation, plus smart warnings for densities outside the physical range (gas-like below 200 kg/m³, water-exceeding above 1000 kg/m³, or beyond the triple-point limit of 654 kg/m³).
Designed for cryogenic-cargo operators verifying tanker manifests, polymer plant engineers calibrating flow meters, chemical-engineering students computing densities from sampled mass and volume, custody-transfer auditors cross-checking metered values against reference data, and any researcher quantifying liquid C₂H₄ samples — the tool runs entirely in your browser, no account, no data stored.
Pro Tip: Pair this with our Molarity Calculator for solution chemistry, our Grams to Moles Calculator for stoichiometry, or our Partial Pressure Calculator for ethylene gas-phase calculations.
How to Use the Liquid Ethylene Density Calculator?
How is liquid ethylene density calculated?
Density is the most-fundamental thermophysical property of a liquid — it is required for converting between mass and volume in every cryogenic-shipping, custody-transfer, and process-engineering calculation. Liquid ethylene density depends strongly on temperature and weakly on pressure (sub-critical liquids are nearly incompressible).
Reference: NIST Chemistry WebBook (Lemmon, McLinden, Friend); IUPAC International Thermodynamic Tables of the Fluid State — Ethylene; CRC Handbook of Chemistry and Physics.
Core Formula
Density ρ = mass / volume
SI standard: kg/m³. Equivalent: 1 g/mL = 1 g/cm³ = 1 kg/L = 1000 kg/m³. US engineering: 1 kg/m³ = 0.06243 lb/ft³ = 0.008345 lb/gal (US).
Liquid Ethylene Reference Density at the 1-atm Boiling Point
ρ_BP = 567.7 kg/m³ = 0.5677 g/mL = 35.44 lb/ft³ = 4.738 lb/gal (US) at T = −103.7 °C = 169.45 K, P = 1.01325 bar.
This is the most-cited value for liquid ethylene; appears in CRC Handbook, NIST WebBook, IUPAC tables, and the safety data sheet of every major industrial-gas supplier.
Worked Example — Tanker-Load Calculation
A cryogenic ethylene tanker has 1500 m³ of liquid C₂H₄ at the 1-atm BP. What is the cargo mass?
- Volume = 1500 m³.
- Density = 567.7 kg/m³.
- Mass = ρ × V = 567.7 × 1500 = 851,550 kg = 851.55 tonnes.
- Equivalent: 30,367 mol/m³ × 1500 m³ = 45.55 Mmol = 45.6 Mmol of C₂H₄.
Worked Example — Sample Density Verification
A cryogenic sample container with tare 200 g, gross weight 760 g, internal volume exactly 1.0 L. Compute density.
- Net mass = 760 − 200 = 560 g = 0.560 kg.
- Volume = 1.0 L = 0.001 m³.
- ρ = 0.560 / 0.001 = 560 kg/m³.
- Deviation vs 567.7 reference = (560 − 567.7) / 567.7 × 100 = −1.36%.
- Interpretation: sample is at slightly elevated T (~−98 °C) or slightly contaminated; well within typical commercial-grade tolerance (±2-3%).
Liquid Ethylene Density vs Temperature (Saturated Liquid)
- Triple point (−169.2 °C / 104.0 K): ρ ≈ 654.4 kg/m³ (densest liquid form).
- −150 °C (123 K): ρ ≈ 632 kg/m³.
- −130 °C (143 K): ρ ≈ 605 kg/m³.
- 1-atm BP (−103.7 °C / 169.45 K): ρ = 567.7 kg/m³ (canonical reference).
- −80 °C (193 K): ρ ≈ 525 kg/m³ (requires elevated pressure ~9 bar).
- −40 °C (233 K): ρ ≈ 437 kg/m³ (requires ~18 bar).
- 0 °C (273 K): ρ ≈ 295 kg/m³ (requires ~40 bar — close to critical).
- Critical point (+9.20 °C / 282.4 K, 50.42 bar): ρ_c = 214.2 kg/m³ (above this, supercritical fluid).
Density vs Other C₂ Hydrocarbons (saturated liquid at 1-atm BP)
- Ethylene (C₂H₄, ethene), BP −103.7 °C: 567.7 kg/m³.
- Ethane (C₂H₆), BP −88.6 °C: 544.0 kg/m³.
- Acetylene (C₂H₂), sublimes at −84 °C: 467 kg/m³ (only below triple point).
- Liquid methane (CH₄), BP −161.5 °C: 422.6 kg/m³.
- Liquid propane (C₃H₈), BP −42.1 °C: 581.0 kg/m³.
- Liquid water at 25 °C: 997.0 kg/m³ (~1.76× ethylene).
Unit Conversion Reference
- 1 kg/m³ = 0.001 g/mL = 0.001 g/cm³ = 0.001 kg/L.
- 1 kg/m³ = 0.062428 lb/ft³.
- 1 kg/m³ = 0.0083454 lb/gal (US) = 0.010022 lb/gal (UK / Imperial).
- 1 g/mL = 1000 kg/m³ = 62.428 lb/ft³ = 8.3454 lb/gal (US).
- 567.7 kg/m³ = 0.5677 g/mL = 35.44 lb/ft³ = 4.738 lb/gal (US) = 5.692 lb/gal (UK).
Worked Example — Cryogenic Tanker Cargo Verification
Scenario. An ISO-tank-container of cryogenic liquid ethylene arrives at a polymer plant. The tank has internal volume 24,000 L (24 m³) at its design temperature of −104 °C; the gross weight is measured as 18,400 kg, and the empty (tare) weight is 4,800 kg.
Step 1 — Compute Net Mass.
- m = 18,400 − 4,800 = 13,600 kg of liquid ethylene.
Step 2 — Apply ρ = m / V.
- V = 24,000 L = 24 m³.
- ρ = 13,600 / 24 = 566.67 kg/m³.
- Or equivalently: ρ = 0.5667 g/mL = 35.36 lb/ft³ = 4.729 lb/gal (US).
Step 3 — Compare to Reference.
- Reference at −103.7 °C BP: 567.7 kg/m³.
- Deviation: (566.67 − 567.7) / 567.7 × 100 = −0.18%.
- Interpretation: cargo density is within 0.2% of the BP reference — consistent with well-controlled cryogenic storage. Mass and volume are mutually consistent; the tanker is properly loaded.
Step 4 — Mole Inventory for Process Calculations.
- n = m / MW = 13,600 / 28.054 = 484,750 mol = 484.75 kmol.
- If polymerized to PE at 100% efficiency: yield = 484.75 × 28.05 = 13,597 kg ≈ 13.6 tonnes (mass conservation).
- At a typical PE plant throughput of 50 tonnes/h, this tank supplies ~16 minutes of feedstock.
Who Should Use the Liquid Ethylene Density Calculator?
Technical Reference
Compound Identity. Ethylene (IUPAC: ethene; CAS 74-85-1; UN 1038 for refrigerated liquid), C₂H₄, MW 28.054 g/mol, formula H₂C=CH₂. Simplest alkene; planar molecule with C=C double bond. Major source: steam cracking of ethane, propane, naphtha. Industrial uses: polyethylene (~60% of production), ethylene oxide → ethylene glycol (~20%), vinyl chloride (~7%), styrene (~5%), ethanol via hydration (~3%).
Phase Diagram Reference Points.
- Triple point: T_t = 104.0 K = −169.2 °C; P_t = 1.213 mbar = 121.3 Pa. Liquid coexists with solid and vapor.
- Normal boiling point (1 atm = 1.01325 bar): T_NBP = 169.45 K = −103.7 °C. Liquid ρ = 567.7 kg/m³; vapor ρ = 2.114 kg/m³.
- Critical point: T_c = 282.35 K = +9.20 °C; P_c = 50.418 bar; ρ_c = 214.2 kg/m³. Above the critical T, ethylene is supercritical for any pressure.
- Density of saturated liquid is correlated by the Span-Wagner-style equation of state implemented in NIST REFPROP and the IUPAC International Thermodynamic Tables — Ethylene, accurate to ±0.05% in the liquid region.
Saturated Liquid Density vs Temperature (NIST REFPROP).
- 104.0 K (TP): 654.4 kg/m³
- 120 K: 638.2 kg/m³
- 140 K: 615.6 kg/m³
- 160 K: 587.1 kg/m³
- 169.45 K (NBP): 567.7 kg/m³
- 180 K: 553.2 kg/m³
- 200 K: 519.0 kg/m³
- 220 K: 477.7 kg/m³
- 240 K: 425.2 kg/m³
- 260 K: 354.8 kg/m³
- 275 K: 290.6 kg/m³
- 282.35 K (CP): 214.2 kg/m³
Pressure Effect on Density (sub-critical liquid). Liquid ethylene is nearly incompressible: at constant T, increasing P from saturation pressure to 100 bar increases ρ by less than 1%. For T = 169.45 K (NBP) and P up to 50 bar: ρ ≈ 567.7 + 0.5%. For most engineering work, the saturated-liquid density at the storage T is sufficient.
Comparison Densities (SI, saturated liquid at 1-atm BP unless noted).
- Ethylene C₂H₄: 567.7 kg/m³
- Ethane C₂H₆: 544.0 kg/m³
- Methane CH₄: 422.6 kg/m³
- Propane C₃H₈: 581.0 kg/m³
- Butane C₄H₁₀: 600.7 kg/m³
- Liquid nitrogen N₂ (BP −196 °C): 808.6 kg/m³
- Liquid oxygen O₂ (BP −183 °C): 1141 kg/m³
- Liquid argon Ar (BP −185.8 °C): 1395.4 kg/m³
- Liquid water (25 °C): 997.0 kg/m³
- Liquid mercury Hg (25 °C): 13,533 kg/m³
Density Measurement Methods. (1) Pycnometer: calibrated-volume vessel; weigh full minus empty. Standard for laboratory work; accuracy ±0.1% with care. (2) Vibrating-tube densitometer (Anton Paar, Mettler): resonant frequency of a U-tube changes with sample density. Accuracy ±0.0001 g/mL (industry standard for QC). (3) Hydrometer: buoyancy-based; reads density off a calibrated scale. Accuracy ±0.5%. (4) Buoyancy weighing (Mohr-Westphal balance): weighs a sinker in the liquid. Accuracy ±0.05%. (5) For cryogenic liquids, commercial densitometers must be jacketed and pre-cooled; alternative: weigh a known volume of liquid in a bath at controlled T.
Safety, Hazards, and Handling. Ethylene is highly flammable (flash point −136 °C, autoignition 450 °C, flammable range 2.7-36 vol% in air, MIE 0.07 mJ — extremely low static-spark ignition energy) and a simple asphyxiant (no toxic effects, but displaces O₂). Cryogenic liquid contact causes severe frostbite (boil-off generates dense vapor that hugs the ground). Major hazards: BLEVE (boiling liquid expanding vapor explosion) if a pressurized liquid tank is fire-impinged; static-spark ignition during cryogenic transfer; oxygen-deficient atmosphere in confined spaces near a leak. Required: bond/ground all transfer equipment; use cold-resistant PPE (face shield, cryogenic gloves, sleeves); flammable-gas detector (set 10% LEL alarm); never seal a heated cylinder. Storage: refrigerated to −104 °C at near-atmospheric pressure (LIN-jacketed tanks) or at +5 to +10 °C under 50-100 bar pressure (less common; energy cost). Reference SDS: Praxair / Linde / Air Liquide / Air Products ethylene SDS — all align on these specifications.
Conclusion
Three pitfalls worth flagging: (1) Confusing ethylene (C₂H₄, the polymer feedstock) with ethylene oxide (C₂H₄O, oxirane — a different compound with very different density 882 kg/m³) or ethanol (C₂H₆O, density 789 kg/m³ at 25 °C) is a documented incident-causing error. (2) Density is highly T-dependent — a 10 °C rise from BP gives ~3% density drop; for off-BP storage use the NIST REFPROP equation of state, not the BP reference. (3) Liquid ethylene is highly flammable (LEL 2.7%, MIE 0.07 mJ — extremely low) and a simple asphyxiant; cryogenic skin contact causes severe frostbite. Always handle with proper PPE, bonding, grounding, and cold-resistant equipment.
Frequently Asked Questions
What is the Liquid Ethylene Density Calculator?
Pro Tip: Pair this with our Molarity Calculator for solution chemistry.
What is the density of liquid ethylene?
Why is liquid ethylene less dense than water?
At what temperature is ethylene a liquid?
How does liquid ethylene density change with temperature?
How do I convert kg/m³ to g/mL or lb/ft³?
Is the density at the boiling point the same at all pressures?
How do I compute the mass of ethylene in a cryogenic tank?
How is liquid ethylene shipped and stored industrially?
What's the difference between ethylene, ethylene oxide, and ethanol?
What are the main safety hazards of liquid ethylene?
Disclaimer
Density ρ = mass / volume. Liquid ethylene (C₂H₄) exists only between its triple point (−169.2 °C, 1.213 mbar) and critical point (+9.20 °C, 50.42 bar); above the critical point ethylene is supercritical, not a true liquid. Reference density 567.7 kg/m³ at the 1-atm BP (−103.7 °C); density varies strongly with T (654 at TP → 214 at CP). Use NIST REFPROP for off-BP T-dependent reference values. Liquid ethylene is highly flammable (LEL 2.7%, MIE 0.07 mJ — extremely low ignition energy) and a simple asphyxiant; cryogenic contact causes severe frostbite. Never confuse with ethylene oxide (C₂H₄O, 882 kg/m³, toxic carcinogen) or ethanol (C₂H₆O, 789 kg/m³). References: NIST Chemistry WebBook (Lemmon, McLinden, Friend); IUPAC International Thermodynamic Tables — Ethylene; CRC Handbook of Chemistry and Physics.